EFFEC T A T LO W PRESSURES 19
entirely changes. At these low pressures It Is exceedingly
difficult to get the discharge to pass through tubes of
moderate size when the cathodes are made of aluminium or
any of the metals ordinarily used for this purpose, and there Is
great danger of sparks passing through the glass and breaking
the tube. This can be avoided to a great extent by facing
the cathode with a thin layer of calcium, or smearing the face
of the cathode with the liquid alloy of sodium and potassium.
This reduces considerably the difficulty of getting the dis-
charge to pass and diminishes the risk of perforating the tube.
The appearance at these low pressures when hydrogen or air
is In the tube Is shown In Fig. 9. It will be noticed that the
straight bands of phosphorescence have
almost disappeared and that most of
phosphorescent light Is concentrated Into
two parabolic curves which are connected
with the undeflected spot by straight faintly
luminous lines. The value of ejm for one
parabola is io4, that for the other 5 x io3
*
so that they are due to the atom and FlG< g
molecule of - hydrogen respectively. At
these low pressures the luminosity In the negative direction
disappears. But both at the low and higher pressure there
is, even when the magnetic and electric fields are in action,
an appreciable amount of luminosity at the position occupied
by the undeflected spot

There is considerable advantage in using very large glass
vessels for the discharge tubes when studying positive rays;
with large vessels the pressure can be made very small before
the tube offers great resistance to the passage of the discharge
through It The increase in the difficulty of getting the
discharge to pass comes in at the pressure when the dark
space round the cathode reaches the walls of the tube. When